SYNTHESIS OF STAR POLY(4-VINYLPYRIDINE) ARCHITECTURE BY NITROXIDE MEDIATED POLYMERISATION

Nurulsaidah Abdul, Rahim and Fabrice, Audouin and Johannes G, Vos and Andreas, Heise (2014) SYNTHESIS OF STAR POLY(4-VINYLPYRIDINE) ARCHITECTURE BY NITROXIDE MEDIATED POLYMERISATION. Proceeding of International Conference On Research, Implementation And Education Of Mathematics And Sciences 2014. (Submitted)

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Abstract

This study proposed multifunctional alkoxyamine 2-({tert-butyl [[1- (diethoxyphosphoryl)-2,2-dimethylpropyl]amino}oxy)-2-methylpropanoic acid (MAMA-SG1) initiators for the ‘grafting-from’ method to obtain star architecture of poly 4-vinylpyridine (P4VP) from JEFFAMINE®. The structure of macroinitiator was confirmed by amide bond present in NMR and FTIR spectroscopy. Furthermore, the macroinitiator was used to polymerise 4VP. P4VP from JEFFAMINE-SG1 shows a monomodal peak in the SEC chromatogram, indicating more control polymerisation process.

Item Type: Article
Uncontrolled Keywords: Nitroxide Mediated Polymerisation, 4-vinylpyridine, star polymer
Subjects: Prosiding > ICRIEMS 2014 > CHEMISTRY & CHEMISTRY EDUCATION
Divisions: Fakultas Matematika dan Ilmu Pengetahuan Alam > Jurusan Pendidikan Kimia > Kimia
Depositing User: Eprints
Date Deposited: 06 Nov 2014 08:55
Last Modified: 06 Nov 2014 08:55
URI: http://eprints.uny.ac.id/id/eprint/11384

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