TY - JOUR UR - http://fmipa.uny.ac.id ID - UNY11426 AV - public TI - EFFECT ACTIVATION OF CHEMICAL AND PHYSICAL TO STRUCTURE AND ACTIVATED CARBON QUALITY FROM CHARCOAL OBTAINED BY PYROLYSIS OF COCONUT SHELL KW - coconut shell KW - activated carbon KW - ZnCl2 KW - SPSS KW - FTIR KW - SEM KW - BET PB - Yogyakarta State University A1 - Djefry, Tani A1 - Bambang, Setiaji A1 - Wega, Trisunaryanti A1 - Akhmad, Syoufian Y1 - 2014/05// N2 - Activation of coconut shell charcoal has been done by a combination of chemical and physical activation to determine the effect of chemical activators and activation temperature to changes in the chemical structure and the quality of activated carbon . The study was conducted on charcoal coconut shell of pyrolysis results with variation of concentration and immersion time ZnCl2 as an activator , respectively 0.5 to 2 M for 12 to 24 hours . Then proceed with the activation of physics in reactor the activation of the temperature variation of 500 to 800 oC with CO2 gas flow rate 20 mL / min . Evaluation of the chemical structure and the quality of activated carbon performed FTIR , SEM , specific surface area , total pore volume , and average pore with Brunauer - Emmett - Teller ( BET ) . The results showed the results of the analysis of SPSS through Cofficients test the concentration variables most affect to moisture content , ash content , and iodine absorption from temperature variable and time of activation . The best quality activated carbon produced at a concentration of ZnCl2 of 1.5 M, 24 hours soaking time of 24 hours , temperature 800 oC and the activation time of 120 minutes . The results as moisture content of 8.47 % , volatile matter content of 18.55 % , ash content 1.44 % , bonded carbon content of 80.01 % and iodine absorption of 769.74 mg / g . The results of FTIR analysis showed the surface of activated carbon containing CO and CH bonds , and SEM analysis showed the number and diameter of pores increased with the higher calcination temperature . Surface area ( BET ) of 359.286 m2 / g , pore volume of 1.984 x 10-1 cm3 / g and pore mean of 11.46 ? . JF - Proceeding of International Conference On Research, Implementation And Education Of Mathematics And Sciences 2014 ER -