%X This study proposed multifunctional alkoxyamine 2-({tert-butyl [[1- (diethoxyphosphoryl)-2,2-dimethylpropyl]amino}oxy)-2-methylpropanoic acid (MAMA-SG1) initiators for the ‘grafting-from’ method to obtain star architecture of poly 4-vinylpyridine (P4VP) from JEFFAMINE®. The structure of macroinitiator was confirmed by amide bond present in NMR and FTIR spectroscopy. Furthermore, the macroinitiator was used to polymerise 4VP. P4VP from JEFFAMINE-SG1 shows a monomodal peak in the SEC chromatogram, indicating more control polymerisation process. %A Rahim Nurulsaidah Abdul %A Audouin Fabrice %A Vos Johannes G %A Heise Andreas %K Nitroxide Mediated Polymerisation, 4-vinylpyridine, star polymer %L UNY11384 %T SYNTHESIS OF STAR POLY(4-VINYLPYRIDINE) ARCHITECTURE BY NITROXIDE MEDIATED POLYMERISATION %D 2014 %J Proceeding of International Conference On Research, Implementation And Education Of Mathematics And Sciences 2014 %I Yogyakarta State University