%0 Journal Article
%A Nurulsaidah Abdul, Rahim
%A Fabrice, Audouin
%A Johannes G, Vos
%A Andreas, Heise
%D 2014
%F UNY:11384
%I Yogyakarta State University
%J Proceeding of International Conference On Research, Implementation And Education Of Mathematics And Sciences 2014
%K Nitroxide Mediated Polymerisation, 4-vinylpyridine, star polymer
%T SYNTHESIS OF STAR POLY(4-VINYLPYRIDINE) ARCHITECTURE BY  NITROXIDE MEDIATED POLYMERISATION
%U http://eprints.uny.ac.id/11384/
%X This study proposed multifunctional alkoxyamine 2-({tert-butyl [[1-  (diethoxyphosphoryl)-2,2-dimethylpropyl]amino}oxy)-2-methylpropanoic acid  (MAMA-SG1) initiators for the ‘grafting-from’ method to obtain star architecture of  poly 4-vinylpyridine (P4VP) from JEFFAMINE®. The structure of macroinitiator  was confirmed by amide bond present in NMR and FTIR spectroscopy.  Furthermore, the macroinitiator was used to polymerise 4VP. P4VP from  JEFFAMINE-SG1 shows a monomodal peak in the SEC chromatogram, indicating  more control polymerisation process.