@article{UNY11384, year = {2014}, publisher = {Yogyakarta State University}, month = {May}, journal = {Proceeding of International Conference On Research, Implementation And Education Of Mathematics And Sciences 2014}, title = {SYNTHESIS OF STAR POLY(4-VINYLPYRIDINE) ARCHITECTURE BY NITROXIDE MEDIATED POLYMERISATION}, author = {Rahim Nurulsaidah Abdul and Audouin Fabrice and Vos Johannes G and Heise Andreas}, abstract = {This study proposed multifunctional alkoxyamine 2-(\{tert-butyl [[1- (diethoxyphosphoryl)-2,2-dimethylpropyl]amino\}oxy)-2-methylpropanoic acid (MAMA-SG1) initiators for the ?grafting-from? method to obtain star architecture of poly 4-vinylpyridine (P4VP) from JEFFAMINE?. The structure of macroinitiator was confirmed by amide bond present in NMR and FTIR spectroscopy. Furthermore, the macroinitiator was used to polymerise 4VP. P4VP from JEFFAMINE-SG1 shows a monomodal peak in the SEC chromatogram, indicating more control polymerisation process.}, keywords = {Nitroxide Mediated Polymerisation, 4-vinylpyridine, star polymer}, url = {http://eprints.uny.ac.id/11384/} }